By S. W. Koch
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Extra resources for Dynamics of First-Order Phase Transitions in Equilibrium and Nonequilibrium Systems
Example text
M o n o l a y e r s for a gene- of n u c l e a t i o n understanding a quantitative in the p r e v i o u s in general. in d i f f e r e n t A possible qualitative However, of the d i m e n s i o n a l i t y . transitions dependence, a is an ansatz theories is still missing. of the results phase model of the c l a s s i c a l separation. 2 Phase T r a n s i t i o n s Most theoretical and u n i f i c a t i o n which have is the c o m m e n s u r a t e - of the adsorbate. 2a The S o l i d - L i q u i d Phase T r a n s i t i o n F r e e z i n g and m e l t i n g are physical effects which are w e l l - k n o w n daily life.
57) are given in Ref. 90 in Eqs. 35, respectively. 56) Eng , ~ng and Eng_c,and Ong_c , Eqs. 53), and constitute the n u m e r i c a l m o d e l for noble gas films on a gra- phite substrate. In the f o l l o w i n g p a r a g r a p h s some of the s i m u l a t i o n results for x e n o n on g r a p h i t e will be d i s c u s s e d [88,89] . 27 shows the g e o m e t r y of the c o m p u t a t i o n a l cell. 27: G e o m e t r y of the c o m p u t a t i o n a l box for the s i m u l a t i o n of noble gas films on graphite.
The intervals factor S(k,T) This yields g(r,T) for Ar and correspondingly the time dependent structure at discrete points in k-space. 11. The full lines are obtained theoretically from the LBM analysis [41] . The agreement be- tween simulation and theory is quite satisfactory. More details of the results of the MC simulations will be discussed at the end of the following chapter in comparison to the findings of molecular dynamics 32 • ,I . . . ; " • '. . . . . . 2 ~.. 1 • ! • ; • i • ! • v • !