Fluid Transport in Nanoporous Materials: Proceedings of the by Wm. Curtis Conner, Jacques Fraissard

By Wm. Curtis Conner, Jacques Fraissard

This NATO ASI concerned teachings and views of the cutting-edge in experimental and theoretical understandings of shipping in nanoporous solids. This workshop introduced jointly the head scientists and engineers in each one sector to debate the similarities and modifications in each one process and conception. The lectures really bridge the gaps among those similar components and ways. The purposes in destiny separations, catalysis, the surroundings and effort wishes are visible. The solids comprised the newly constructing molecular sieves, organic platforms and polymeric solids. shipping in unmarried debris, in membranes and in advertisement functions have been reviewed and analyzed, putting each one in context. thoughts akin to uptake, Chromatographic, Frequency reaction, NMR, Neutron Scattering and Infrared spectroscopies are mentioned for combinations in addition to for unmarried elements. Theoretical methods reminiscent of Density practical conception, Statistical Mechanics, Molecular Dynamics and Maxwell-Stefan concept are hired to investigate the diffusional delivery in restricted environments, spanning from sub-nanometers to centimetre scales. In all circumstances the theories are on the topic of the experiments. those lectures current a uniquq chance to benefit a number of the theoretical and experimental techniques to investigate and comprehend delivery in nanoporous fabrics.

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Extra resources for Fluid Transport in Nanoporous Materials: Proceedings of the NATO Advanced Study Institute, held in La Colle sur Loup, France, 16-28 June 2003 (NATO ... II: Mathematics, Physics and Chemistry)

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Each has analogue in the measurement of nanoporous materials that can be viewed in Rees’ work with frequency response in zeolites. The apparatus shown below is a barometric device that can be used in frequency or step response mode. One can make a step change in the volume of the system (say, 3%) and examine the pressure decay as the sorbent polymer seeks it equilibrium state. The decay curve can be analyzed exactly as one might with gravimetric experiments. Duda and his group [38] have developed another pair of barometric apparatus to measure diffusivities.

Cohen and Turnbull [17] and Turnbull and Cohen [18] gave the free volume theory its first theoretical basis by developing an expression relating the self-diffusion coefficient to the free volume for a liquid of hard spheres. Their theory is based on the concept that molecular diffusion occurs by the movement of molecules into voids formed by a random redistribution of the free volume within the material. Naghizadeh [19] proposed a modified version of the Cohen-Turnbull theory by considering a redistribution energy for the voids in the system.

28. Phelps, D. M. (2001) Adsorption 7, 221-229. 29. , Dereppe, J-M. and Fraissard, J. (2001) Studies in Surf-Sci and Control 135, 93-102. A. Galarneau, F. DiRenzo, F. Fajula and J. , Elsevier, New York. 30. , Kerhof, J. and Kopinga, K. (2000) Proc. 2nd Pacific Conf. on Adsorption p. D. , World Scientific, Singapore. 31. J. M. (2002) Ind. Eng. Chem. Res. 41, 2320-2329. MEASUREMENT OF DIFFUSION IN MACROMOLECULAR SYSTEMS: SOLUTE DIFFUSION IN POLYMERS SYSTEMS R. L. edu Abstract Diffusion is a macroscopic process by which relative motion takes place between the components of a mixture.

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